Benthic geochemistry of manganese in the Bay of Biscay,and sediment mass accumulation rate     

Aurélia Mouret  Pierre Anschutz  Pascal Lecroart  Gwénaëlle Chaillou  Christelle Hyacinthe  Jonathan Deborde  Frans J. Jorissen  Bruno Deflandre  Sabine Schmidt  Jean-Marie Jouanneau 《Geo-Marine Letters》2009,29(3):133-149

Manganese is a major redox reactive element of benthic metabolism. We have built a database of existing knowledge on the benthic geochemistry of Mn in the Bay of Biscay, in order to comprehensively assess the behaviour of Mn in a variety of environments during early diagenesis. The database contains vertical profiles of particulate and dissolved Mn species of 59 cores collected during 17 cruises between 1997 and 2006 at nine stations positioned between 140 and 4,800 m water depths. At all studied stations, Mn species follow the conventional distribution, where Mn(III,IV) species are enriched in the oxic layer, and dissolved Mn is present in the anoxic sediments. A minor part of Mn-oxides originates from sedimenting particles. The major part is of diagenetic origin, and derives from the oxidation of upward-diffusing dissolved Mn(II). Mn-oxide inventories are higher at the deeper stations than at the shallower ones. This difference cannot be attributed to different sources of sedimenting particles, but it must depend on sedimentation rate and diagenetic processes. At depth, dissolved Mn(II) concentrations are constant. This probably reflects equilibrium with an authigenic Mn(II) phase, which is the ultimate phase into which Mn is fossilized. The Mn content of deeper anoxic sediments is similarly low in all the cores studied, associated with corresponding trends of Mn content in sedimenting particles of the Bay of Biscay. Bioturbation, rather than redox oscillations, can convey Mn(III,IV) species downwards into the anoxic sediments where they are reduced, associated with a peak of dissolved Mn. Because dissolved Mn(II) is re-oxidized when it diffuses towards the oxic layer, the inventory of the diagenetic Mn(III,IV) phase remains at steady state, especially at stations where the oxic layer is thick. It then becomes possible to calculate the residence time of diagenetic Mn(III,IV) particles within the oxic layer, using the upward-directed flux of pore water Mn(II). By applying this residence time to the accumulation of sediments within the oxic layer, we obtain the sediment mass accumulation rate. The values calculated for the sediments of the Bay of Biscay fit well with accumulation rates obtained from radionuclides or sediment traps. The method has also been validated with data collected in other marine sedimentary environments. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

Oxidation modes and thermodynamics of Fe oxyhydroxycarbonate green rust: Dissolution-precipitation versus in situ deprotonation     

Christian Ruby  Mustapha Abdelmoula  Aurélien Renard  Georges Ona-Nguema  Jean-Marie R. Génin 《Geochimica et cosmochimica acta》2010,74(3):953-966

Fe^II-III hydroxycarbonate green rust GR(CO₃²⁻), Fe^II₄ Fe^III₂ (OH)₁₂ CO₃·3H₂O, is oxidized in aqueous solutions with varying reaction kinetics. Rapid oxidation with either H₂O₂ or dissolved oxygen under neutral and alkaline conditions leads to the formation of ferric oxyhydroxycarbonate GR(CO₃²⁻)∗, Fe^III₆ O₁₂ H₈ CO₃·3H₂O, via a solid-state reaction. By decreasing the flow of oxygen bubbled in the solution, goethite α-FeOOH forms by dissolution-precipitation mechanism whereas a mixture of non-stoichiometric magnetite Fe_(3−x)O₄ and goethite is observed for lower oxidation rates. The intermediate Fe^II-III oxyhydroxycarbonate of formula Fe^II_6(1−x) Fe^III_6x O₁₂ H_2(7−3x) CO₃·3H₂O, i.e. GR(x)∗ for which x ? [1/3, 1], is the synthetic compound that is homologous to the fougerite mineral present in hydromorphic gleysol; in situ oxidation accounts for the variation of ferric molar fraction x = [Fe^III]/{[Fe^II]+[Fe^III]} observed in the field as a function of depth and season but limited to the range [1/3, 2/3]. The domain of stability for partially oxidized green rust is observed in the E_h-pH Pourbaix diagrams if thermodynamic properties of GR(x)∗ is compared with those of lepidocrocite, γ-FeOOH, and goethite, α-FeOOH. Electrochemical equilibrium between GR(x)∗ and Fe^II in solution corresponds to E_h-pH conditions close to those measured in the field. Therefore, the reductive dissolution of GR(x)∗ can explain the relatively large concentration of Fe^II measured in aqueous medium of hydromorphic soils containing fougerite.  相似文献   

Surface chemistry and structural properties of mackinawite prepared by reaction of sulfide ions with metallic iron     

Martine Mullet  Sophie BoursiquotMustapha Abdelmoula  Jean-Marie GéninJean-Jacques Ehrhardt 《Geochimica et cosmochimica acta》2002,66(5):829-836

Tetragonal FeS_1−x mackinawite, has been synthesized by reacting metallic iron with a sodium sulfide solution and characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), transmission Mössbauer spectroscopy (TMS) and X-ray photoelectron spectroscopy (XPS). Based on XRD and TEM analyses, synthetic mackinawite exhibits crystallization and is identical to the natural mineral. Unit cell parameters derived from XRD data are a = b = 0.3670 nm and c = 0.5049 nm. The bulk Fe:S ratio derived from the quantitative dispersive energy analysis is practically 1. XPS analyses, however, showed that mackinawite surface is composed of both Fe(II) and Fe(III) species bound to monosulfide. Accordingly, monosulfide is the dominant S species observed at the surface with lesser amount of polysulfides and elemental sulfur. TMS analysis revealed the presence of both Fe(II) and Fe(III) in the mackinawite structure, thus supporting the XPS analysis. We propose that the iron monosulfide phase synthesized by reacting metallic iron and dissolved sulfide is composed of Fe(II) and S(-II) atoms with the presence of a weathered thin layer covering the bulk material that consists of both Fe(II) and Fe(III) bound to S(-II) atoms and in a less extent of polysulfide and elemental sulfur.  相似文献   

Geochemical characteristics of an intracontinental shoshonitic association: the example of the Damavand volcano,IranCaractéristiques géochimiques d'une association shoshonitique intracontinentale : exemple du Damavand,Iran     

Hossein Mehdizadeh  Jean-Michel Liotard  Jean-Marie Dautria 《Comptes Rendus Geoscience》2002,334(2):111-117

Lavas of the Quaternary Damavand volcano (Central Alborz, Northern Iran) have been analysed for major and trace elements. The shoshonitic character of this magmatic series is definitively confirmed and most samples correspond to banakites. The Nb, Ta and Ti negative anomalies observed in all lavas suggest that they derive from of a sub-continental lithosphere metasomatised in a subduction setting. Their variable trace element enrichments are explained both by mineral fractionation and by crustal contamination in a shallow magmatic chamber. To cite this article: H. Mehdizadeh et al., C. R. Geoscience 334 (2002) 111–117.  相似文献   

Analyse d'Image pour l'Évaluation de l'Exposition de la Côte à l'Action des Vagues     

Élizabeth L. Simms  Alvin E. Simms  & Jean-Marie M. Dubois 《Geografiska Annaler: Series A, Physical Geography》1997,79(3):167-176

A method of analysis was developed to estimate wind-induced wave heights in the coastal zone. The analysis is based on a digital bathymetry model in raster format. The model uses wind characteristics such as direction, velocity, and fetch. In addition, underwater terrain slope magnitude and orientation, and water depth are used in the computation of the model to estimate wave heights. Two analyses are shown, taking into account waves built from short fetch wind and indefinite fetch wind. The analysis was applied to Hare Bay in northern Newfoundland. First, we take into account a northerly wind of 6.9 ms⁻¹ where the fetch is 19 km or less. The estimated wave heights vary between 0 and 0.5 m. With the second application, we considered an indefinite ESE fetch wind of 17.8 ms⁻¹. In this case, the wave heights resulting from the application of the model vary between 0 and 11.8 m. We compared the modelling results based on ESE wind and the wave energy derived through visual analysis. Relationships were identified between the wave height classes and the wave energy categories.  相似文献